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The only reason that I can think of is that the values are outside those calculated by this method- as you suggest, it may not be appropriate for these compounds. I've seen similar things happen in HYSYS (dew point curve without bubble point curve) when there are hypothetical components present in the material stream. ![]() I've found the entry for this, it just won't return a value. ![]() ![]() I'm after the ASTM D93 standard closed cup flash point, which I believe is the default value HYSYS gives. Thanks for that, I want to look at mixtures with other components under a range of conditions added in as well, which is why I'm looking at using HYSYS- have you any suggestions for more accurate predictions if HYSYS isn't likely to be up to the job? ASTM) is applicable for the type of compounds/chemicals you are interested in. 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